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[{Cp(CO) 2 Mn} 2 (μ‐H)] ⊖ : A New, Versatile Reagent
Author(s) -
Plößl Karl,
Huttner Gottfried,
Zsolnai Laszlo
Publication year - 1989
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198904461
Subject(s) - reagent , chemistry , metal , manganese , crystallography , stereochemistry , medicinal chemistry , organic chemistry
The first anionic reagent for the introduction of the 16‐electron species Cp(CO) 2 Mn , the title compound 1 , was obtained by reaction of [Cp(CO) 2 Mn(thf)] with NaBH 4 . The Cp′ analogue of 1 (Cp′ = η 5 ‐MeC 5 H 4 ) reacts with BiCl 3 to give the complex 2 . This is the first complex with side‐on–coordinated Bi 2 involving a 3d metal center.