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(C 4 Me 4 NBH 3 ) 2 Fe—a Metal Complex Isosteric with Decamethylferrocene with Characteristic Metallocene Disorder
Author(s) -
Kuhn Norbert,
Horn EvaMaria,
Boese Roland,
Augart Norbert
Publication year - 1989
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198903421
Subject(s) - acentric factor , crystallography , boron , metallocene , ligand (biochemistry) , metal , chemistry , atom (system on chip) , nitrogen , materials science , inorganic chemistry , organic chemistry , biochemistry , receptor , computer science , embedded system , polymerization , polymer
An acentric coordination of the trihydro(tetramethylpyrrolyl) borato ligand in 1 is effected by the “small” nitrogen atom. Like the isosteric decamethylferrocene, 1 is disordered by shifting and rotation of the C 5 axis in the crystal. The novel ligand of 1 could be incorporated at the Fe center of the analogous “boron‐free” complex with Me 2 S·BH 3 .