(C 4 Me 4 NBH 3 ) 2 Fe—a Metal Complex Isosteric with Decamethylferrocene with Characteristic Metallocene Disorder | Zendy

Kuhn Norbert | Zendy; Horn EvaMaria | Zendy; Boese Roland | Zendy; Augart Norbert | Zendy

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(C 4 Me 4 NBH 3 ) 2 Fe—a Metal Complex Isosteric with Decamethylferrocene with Characteristic Metallocene Disorder

Author(s) -

Kuhn Norbert,

Horn EvaMaria,

Boese Roland,

Augart Norbert

Publication year - 1989

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198903421

Subject(s) - acentric factor , crystallography , boron , metallocene , ligand (biochemistry) , metal , chemistry , atom (system on chip) , nitrogen , materials science , inorganic chemistry , organic chemistry , biochemistry , receptor , computer science , embedded system , polymerization , polymer

An acentric coordination of the trihydro(tetramethylpyrrolyl) borato ligand in 1 is effected by the “small” nitrogen atom. Like the isosteric decamethylferrocene, 1 is disordered by shifting and rotation of the C 5 axis in the crystal. The novel ligand of 1 could be incorporated at the Fe center of the analogous “boron‐free” complex with Me 2 S·BH 3 .

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