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Photochemical Formation of a Stable Oxalic Acid Orthoamide with a Propellane Structure
Author(s) -
Tauer Erich,
Grellmann KarlHeinz,
Noltemeyer Mathias,
Sheldrick George M.
Publication year - 1989
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198903381
Subject(s) - oxalic acid , propellane , chemistry , photochemistry , stereochemistry , organic chemistry , bicyclic molecule
The first stable orthoamide of oxalic acid with the substitution pattern of a hexaaminoethane, the “4.4.4” propellane 2 , was obtained by irradiation of 1 in cyclohexane (R = CH 3 ).