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t Bu 2 PPPbr t Bu 2 . LiBr and the Formation of t Bu 2 P
Author(s) -
Fritz Gerhard,
Vaahs Tilo,
Fleischer Holm,
Matern Eberhard
Publication year - 1989
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198903151
Subject(s) - thermal decomposition , chemistry , decomposition , medicinal chemistry , stereochemistry , organic chemistry
Clear indications of the formation of diphosphanediyl t BuPin the thermal decomposition of 1 are the products 2 and 3 as well as those of trapping reactions with 2,3‐dimethyl‐1,3‐butadiene and cyclohexene 4/5 and 6 , respectively.