Do Any AB n  Molecules Have Anomalous Shapes?  v  3  of TiF 4  and TiF 3  and Their Relevance to the Shape of TiF 2 | Zendy

Beatte Ian R. | Zendy; Jones Peter J. | Zendy; Young Nigel A. | Zendy

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Do Any AB n Molecules Have Anomalous Shapes? v 3 of TiF 4 and TiF 3 and Their Relevance to the Shape of TiF 2

Author(s) -

Beatte Ian R.,

Jones Peter J.,

Young Nigel A.

Publication year - 1989

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198903131

Subject(s) - cornerstone , relevance (law) , trigonal crystal system , planar , molecule , element (criminal law) , matrix (chemical analysis) , physics , chemistry , crystallography , political science , computer science , law , quantum mechanics , history , crystal structure , computer graphics (images) , archaeology , chromatography

There is no firm evidence that any first row transition element dihalides are non‐linear. This conclusion is drawn from the fact the IR bands previously assigned to “non‐linear” LiF 2 definitely arise from trigonal planar TiF 3 . Earlier matrix isolation studies, from which a 120°‐TiF 2 had been concluded, formed the cornerstone of the theory of anomalous MF 2 molecules.

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