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The Pagodane Route to Dodecahedranes: Chemistry and Structure of Bissecododecahedranes
Author(s) -
Lutz Georg,
Hunkler Dieter,
Prinzbach Horst,
Rihs Grety
Publication year - 1989
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198902981
Subject(s) - chemistry , dehydrogenation , combinatorial chemistry , organic chemistry , catalysis
An insight into the chemistry of dodecahedranes necessitates access to singly and multiply functionalized derivatives in preparative amounts. The first way failed: several bisseco precursors, including the di‐ and tetra‐substituted derivatives 1 and 2 and the diones 3–5 have been obtained but could not be dehydrogenated to dodecahedrane derivatives.