A Tetraborylphosphonium Ion with a Spiroheterocyclic Structure | Zendy

Driess Matthias | Zendy; Frankhauser Pascal | Zendy; Pritzkow Hans | Zendy; Siebert Walter | Zendy

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A Tetraborylphosphonium Ion with a Spiroheterocyclic Structure

Author(s) -

Driess Matthias,

Frankhauser Pascal,

Pritzkow Hans,

Siebert Walter

Publication year - 1989

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198902171

Subject(s) - crystallography , ion , ionic bonding , crystal structure , planar , chemistry , maltese , ionic compound , stereochemistry , organic chemistry , computer science , linguistics , philosophy , computer graphics (images)

The crystal structure of the cation 1 resembles a Maltese cross. It has planar C 2 B 2 P rings, it is the first compound with BP bonds between λ 5 ,σ 4 ‐P and λ 3 ,σ 3 ‐B atoms, and its compounds with X Cl, BPh 4 are ionic both in the solid and in solution. Cation 1 is formed from RClBCHCHBC1R and P(SiMe 3 ) 3 . R N i Pr 2 .

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