Structure, Deformation Electron Densities, Photoelectron Spectra, and Reactivity of 3,4‐Dihydro‐1 H ‐cyclobuta[ a ]cyclopropa[ d ]benzene | Zendy

Bläser Dieter | Zendy; Boese Roland | Zendy; Brett Waldemar A. | Zendy; Rademacher Paul | Zendy; Schwager Harald | Zendy; Stanger Am | Zendy; Vollhardt K. Peter C. | Zendy

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Structure, Deformation Electron Densities, Photoelectron Spectra, and Reactivity of 3,4‐Dihydro‐1 H ‐cyclobuta[ a ]cyclopropa[ d ]benzene

Author(s) -

Bläser Dieter,

Boese Roland,

Brett Waldemar A.,

Rademacher Paul,

Schwager Harald,

Stanger Am,

Vollhardt K. Peter C.

Publication year - 1989

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198902061

Subject(s) - reactivity (psychology) , benzene , deformation (meteorology) , chemistry , spectral line , crystallography , electron , computational chemistry , stereochemistry , materials science , physics , organic chemistry , quantum mechanics , composite material , medicine , alternative medicine , pathology

One of the most highly strained compounds is the title compound 1 . The X‐ray structure analysis of 1 has now allowed a comparison of 1 with the two “partial structures” 2 and 3 . Compound 1 reacts with the complex [(Me 3 P) 2 Ni(cod)] to give 4 . Surprisingly, competition experiments revealed that 2 reacts faster with the complex than 1 —a finding that can be explained theoretically.

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