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Methylboron Oxide, H 3 CBO
Author(s) -
Bock Hans,
Cederbaum Lorenz,
von Niessen W.,
Paetzold Peter,
Rosmus Pavel,
Solouki Bahman
Publication year - 1989
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198900881
Subject(s) - acetonitrile , chemistry , alkyl , oxide , aryl , medicinal chemistry , stereochemistry , triple bond , double bond , organic chemistry
The title compound can be regarded as an analogue of acetonitrile. It was generated by energetically favorable CO‐ and CO 2 ‐elimination from 2‐methyl‐1,3,2‐dioxaborolane‐4,5‐dione 1 . The CBO skeleton is linear, and a BO triple bond is present. According to the findings of this study, it should be possible to isolate R 3 CBO compounds with bulky alkyl or aryl residues.
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