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A trans ‐Dimethyl Derivative of Octahedral Ti IV : Alkylation and Arylation of Ti IV ‐Schiff Base Complexes
Author(s) -
Floriani Carlo,
Solari Euro,
Corazza Fabio,
ChiesiVilla Angiola,
Guastini Carlo
Publication year - 1989
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198900641
Subject(s) - reagent , octahedron , schiff base , nucleophile , chemistry , ligand (biochemistry) , medicinal chemistry , derivative (finance) , alkylation , stereochemistry , crystallography , catalysis , crystal structure , organic chemistry , biochemistry , receptor , financial economics , economics
The Ti IV ‐complex [(Ti(salen)Cl 2 ] 1 can be attacked by nucleophiles at both the ligand as well as at the central atom. For example, depending on the reagent and conditions, the organotitanium compounds 2 – 4 are formed (salen N,N ′‐ethylenebis(salicylideneiminato)).