A  trans ‐Dimethyl Derivative of Octahedral Ti  IV  : Alkylation and Arylation of Ti IV ‐Schiff Base Complexes | Zendy

Floriani Carlo | Zendy; Solari Euro | Zendy; Corazza Fabio | Zendy; ChiesiVilla Angiola | Zendy; Guastini Carlo | Zendy

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A trans ‐Dimethyl Derivative of Octahedral Ti IV : Alkylation and Arylation of Ti IV ‐Schiff Base Complexes

Author(s) -

Floriani Carlo,

Solari Euro,

Corazza Fabio,

ChiesiVilla Angiola,

Guastini Carlo

Publication year - 1989

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198900641

Subject(s) - reagent , octahedron , schiff base , nucleophile , chemistry , ligand (biochemistry) , medicinal chemistry , derivative (finance) , alkylation , stereochemistry , crystallography , catalysis , crystal structure , organic chemistry , biochemistry , receptor , financial economics , economics

The Ti IV ‐complex [(Ti(salen)Cl 2 ] 1 can be attacked by nucleophiles at both the ligand as well as at the central atom. For example, depending on the reagent and conditions, the organotitanium compounds 2 – 4 are formed (salen N,N ′‐ethylenebis(salicylideneiminato)).

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