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Acyl–Alkylidyne Coupling in the Synthesis of Dinuclear Complexes
Author(s) -
Hart Ian J.,
Jeffery John C.,
Lowry Rachel M.,
Stone F. Gordon A.
Publication year - 1988
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198817031
Subject(s) - chemistry , bridging (networking) , stereochemistry , coupling (piping) , crystallography , materials science , metallurgy , computer science , computer network
The novel complexes 1 and 2 have model character for intermediates of the Fischer‐Tropsch Synthesis. They can be prepared from [Mn(Me)(CO) 5 ] and [M(Me)(CO) 3 (η‐C 5 H 5 )], M Mo, W, respectively, and alkylidynetungsten complexes. 1 has an unusually short WMn bond (2.696(1) Å), probably as a result of the bridging by the RCC(O)Me ligands.