Titanium(0) Arene Complexes: Synthesis and X‐ray Crystal Structure of [η 6 ‐C 10 H 8 Ti{ t BuSi(CH 2 PMe 2 ) 3 }] | Zendy

Gardner Thomas G. | Zendy; Girolami Gregory S. | Zendy

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Titanium(0) Arene Complexes: Synthesis and X‐ray Crystal Structure of [η 6 ‐C 10 H 8 Ti{ t BuSi(CH 2 PMe 2 ) 3 }]

Author(s) -

Gardner Thomas G.,

Girolami Gregory S.

Publication year - 1988

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198816931

Subject(s) - titanium , crystal structure , crystallography , metal , x ray , crystal (programming language) , chemistry , x ray crystallography , physics , materials science , stereochemistry , optics , diffraction , organic chemistry , programming language , computer science

An unusually strong metal‐arene back‐bonding characterizes the bonding in the title complex 1 , which is obtained in the form of deep purple‐red, air‐stable crystals on reduction of [TiCl 3 (trimpsi)(thf)], trimpsi = t BuSi(CH 2 PMe 2 ) 3 , with naphthalenesodium in THF. This 16e‐complex has an overall three‐legged piano‐stool geometry, and the π‐bonded naphthalenring has partial dienediyl character.

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