4‐Iodo‐1,3,5,7‐tetramethyl‐1,3,5,7‐tetraaza‐4λ 5 ‐phosphaspiro[3.3]heptane‐2,6‐dione: Synthesis and Crystal Structure of the First Iodophosphorane | Zendy

Breker Johannes | Zendy; Jones Peter G. | Zendy; Stalke Dietmar | Zendy; Schmutzler Reinhard | Zendy

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4‐Iodo‐1,3,5,7‐tetramethyl‐1,3,5,7‐tetraaza‐4λ 5 ‐phosphaspiro[3.3]heptane‐2,6‐dione: Synthesis and Crystal Structure of the First Iodophosphorane

Author(s) -

Breker Johannes,

Jones Peter G.,

Stalke Dietmar,

Schmutzler Reinhard

Publication year - 1988

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198815621

Subject(s) - heptane , crystal structure , atom (system on chip) , chemistry , crystallography , trigonal crystal system , crystal (programming language) , stereochemistry , organic chemistry , computer science , embedded system , programming language

A trigonal‐bipyramidally coordinated P atom is the characteristic structural element of the title compound 2 , which can be synthesized from the readily available 1 by Cl/I exchange. The crystals of 2 are pale yellow at −30°C, but at room temperature light brown; they decompose above 50°C. The P‐I bond, which is without precedent, is 245.8(3) pm long.

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