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Iodine‐Induced Stereoselective Carbocyclizations: A New Method for the Synthesis of Cyclohexane and Cyclohexene Derivatives
Author(s) -
Barluenga José,
González José M.,
Campos Pedro J.,
Asensio Gregorio
Publication year - 1988
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198815461
Subject(s) - cyclohexane , cyclohexene , iodine , stereoselectivity , simple (philosophy) , chemistry , organic chemistry , combinatorial chemistry , computer science , catalysis , philosophy , epistemology
The ready availability of the starting materials and the extensive possibilities for functionalizing the products are the distinguishing features of the title reaction 1 → 2 , which is shown exemplarily in equation (a). Further advantages are good yields, high diastereoselectivity, and the simple purification of the carbocyclic products.