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Linear Twofold Coordination of Arsenic in [Cp′(CO) 2 MnAsMn(CO) 2 Cp′] ⊕
Author(s) -
Strube Albert,
Huttner Gottfried,
Zsolnai Laszlo
Publication year - 1988
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198815291
Subject(s) - manganese , arsenic , chemistry , atom (system on chip) , crystallography , inorganic chemistry , organic chemistry , computer science , embedded system
An angle of 176.6° at the As atom is found for 1 , and X‐ray studies show that the MnAsMn unit in 2 is also linear. 1 and 2 are thus the first compounds in which an element of the fifth main group exhibits a linear μ 2 ‐coordination; the arrangement of the Mn ligands in 1 is in agreement with the allene‐like formulation MnAsMn.
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