Selective Photochemical Dehydrogenation of Saturated Hydrocarbons with Quantum Yields Approaching Unity | Zendy

Renneke Roman F. | Zendy; Hill Craig L. | Zendy

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Selective Photochemical Dehydrogenation of Saturated Hydrocarbons with Quantum Yields Approaching Unity

Author(s) -

Renneke Roman F.,

Hill Craig L.

Publication year - 1988

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198815261

Subject(s) - dehydrogenation , acetonitrile , alkane , photochemistry , homogeneous , chemistry , redox , quantum chemical , quantum , organic chemistry , hydrocarbon , molecule , physics , thermodynamics , catalysis , quantum mechanics

The homogeneous systems [ n Bu 4 N] 4 [W 10 O 32 ]/strong acid/acetonitrile/alkane is the first polymetallate system which makes possible a photo‐redox chemistry—transformation of light into chemical energy—with high quantum yields. Alkanes are selectively photo‐dehydrogenated by this system using UV light of low energy (λ > 360 nm); reaction 1 → 2 is typical.

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