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Organobimetallic MgPd Complexes as Intermediates in the Formation of Amorphous MgPdC x H y from Mg(C 2 H 5 ) 2 and [Pd(η 3 ‐C 3 H 5 ) 2 ]
Author(s) -
Bogdanović Borislav,
Huckett Sara C.,
Wilczok Ursula,
Rufiǹska Anna
Publication year - 1988
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198815131
Subject(s) - intermetallic , propene , amorphous solid , chemistry , reaction intermediate , group 2 organometallic chemistry , crystallography , inorganic chemistry , analytical chemistry (journal) , materials science , catalysis , molecule , organic chemistry , alloy
1 and 2 were identified by NMR spectroscopy at low temperature as intermediates in the formation of amorphous MgPdC x H y 3 from Mg(C 2 H 5 ) 2 and [Pd(η 3 ‐C 3 H 5 ) 2 ]. The experimentally determined product ratio 3 : ethene:propene:ethane = 1:2:1:1 can be explained on the basis of the formation of a further intermediate from 2 and Mg(C 2 H 5 ) 2 . 3 is of interest as an organometallic precursor for the deposition of intermetallic compounds from the gas phase.