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Solid State Structure of a Lithium Triorganostannate
Author(s) -
Veith Michael,
Ruloff Cornelius,
Huch Volker,
Töllner Fritz
Publication year - 1988
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198813811
Subject(s) - lithium (medication) , stannate , octahedron , ion , tin , coordination sphere , crystallography , chemistry , inorganic chemistry , materials science , crystal structure , organic chemistry , zinc , medicine , endocrinology
The first details of the coordination sphere of lithium triorganostannates have been obtained with lithium tris(α‐furyl)stannate 1 . The compound may be formulated as an ion pair. In the anion, the lithium ion exhibits an unusual, distorted octahedral oxygen coordination. The tin atoms are, as expected, coordinated in a pyramidal fashion.
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