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A Donor Cage with Bent Tetrathiafulvalene Moiety
Author(s) -
Röhrich Jorg,
Wolf Peter,
Enkelmann Volker,
Müllen Klaus
Publication year - 1988
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198813771
Subject(s) - tetrathiafulvalene , bent molecular geometry , moiety , cage , molecule , chemistry , crystallography , stereochemistry , solubility , materials science , organic chemistry , structural engineering , engineering
The chemical and electronic properties of tetrathiafulvalene (TTF) change appreciably when the molecule is bent. In the title compounds 1 , R = OPr or OHex, such a structure is present. The cage compound 1 is readily accessible and the (solubility‐improving) substituents R may be varied.