Novel Layer Structure of Sodium Calix[4]arenesulfonate Complexes—a Class of Organic Clay Mimics? | Zendy

Coleman Anthony W. | Zendy; Bott Simon G. | Zendy; Morley S. David | Zendy; Means C. Mitchell | Zendy; Robinson Kerry D. | Zendy; Zhang Hongming | Zendy; Atwood Jerry L. | Zendy

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Novel Layer Structure of Sodium Calix[4]arenesulfonate Complexes—a Class of Organic Clay Mimics?

Author(s) -

Coleman Anthony W.,

Bott Simon G.,

Morley S. David,

Means C. Mitchell,

Robinson Kerry D.,

Zhang Hongming,

Atwood Jerry L.

Publication year - 1988

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198813611

Subject(s) - sulfonate , sodium , chemistry , layer (electronics) , molecule , salt (chemistry) , crystallography , sodium salt , acetone , ion , inorganic chemistry , polymer chemistry , organic chemistry

The crystalline sodium salt of calix[4]arene‐sulfonate 1 consists of alternating organic and inorganic layers . Double layers of the basketlike pentaanions alternate with layers of sodium ions and water molecules; the similarity with the structures of clays is readily apparent. Acetone is bound in the cavity of 1 , the O atom projecting into the hydrophilic layer (see right).

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