Premium
Convenient Routes to Di‐ tert ‐butylsilanediyl: Chemical, Thermal and Photochemical Generation
Author(s) -
Boudjouk Philip,
Samaraweera Upasiri,
Sooriyakumaran Ratnasabapathy,
Chrusciel Jerzy,
Anderson Kevin R.
Publication year - 1988
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198813551
Subject(s) - yield (engineering) , trapping , ring (chemistry) , photochemistry , chemistry , thermal , materials science , organic chemistry , physics , thermodynamics , ecology , metallurgy , biology
α‐Elimination from 1 and thermal or photochemical cleavages of 2 produce t Bu 2 Si:, the trapping or subsequent products of which can be isolated in good to very good yields. The silanediyl generated from 1a by α‐elimination does not dimerize to t Bu 4 Si 2 , but instead produces the four‐membered ring compound 3 in 15% yield.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom