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Reactions of Pentacarbonyl(trichloromethyl isocyanide)chromium
Author(s) -
Beck Gerhard,
Fehlhammer Wolf P.
Publication year - 1988
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198813441
Subject(s) - isocyanide , dichlorocarbene , chemistry , electrophile , chromium , iron pentacarbonyl , organic chemistry , photochemistry , combinatorial chemistry , catalysis
A broad palette of organometallic compounds can be synthesized from the readily accessible 1 , which exhibits two mutually reinforcing electrophilic centers, the isocyano unit and the halogenated α‐C atom. The high synthetic potential of 1 , as well as its 2‐azaalleniumylidene and dichlorocarbene nature, are exemplified by preparation of 2–4 .
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