A New Approach to Ionic Ozonides | Zendy

Hesse Werner | Zendy; Jansen Martin | Zendy

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A New Approach to Ionic Ozonides

Author(s) -

Hesse Werner,

Jansen Martin

Publication year - 1988

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198813411

Subject(s) - ionic bonding , ozonide , chemistry , alkali metal , tetramethylammonium , inorganic chemistry , organic chemistry , ion , ozonolysis

Tetramethylammonium ozonide, N(CH 3 ) 4 O 3 , is surprisingly stable! It forms red, transparent crystals, which only decompose above 75 °C. Till now, the thermally very labile alkali‐metal ozonides were thought to be the most stable ionic ozonides. The possibility of developing a preparative chemistry involving ionic ozonides was therefore viewed with pessimism. N(CH 3 ) 4 O 3 was synthesized by double reaction of KO 3 with N(CH 3 ) 4 O 2 in NH 3 . This route to ionic ozonides should prove to be general.

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