Synthesis, Structure, and Reactivity of [Mn 2 (μ‐H) 2 (CO) 6 (μ‐Ph 2 PCH 2 PPh 2 )] | Zendy

Alonso Francisco J. García | Zendy; Sanz Manuel García | Zendy; Riera Victor | Zendy; Ruíz Miguel Angel | Zendy; Tiripicchio Antonio | Zendy; Camellini Marisa Tiripicchio | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Synthesis, Structure, and Reactivity of [Mn 2 (μ‐H) 2 (CO) 6 (μ‐Ph 2 PCH 2 PPh 2 )]

Author(s) -

Alonso Francisco J. García,

Sanz Manuel García,

Riera Victor,

Ruíz Miguel Angel,

Tiripicchio Antonio,

Camellini Marisa Tiripicchio

Publication year - 1988

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198811671

Subject(s) - reactivity (psychology) , intermolecular force , chemistry , manganese , crystallography , molecule , organic chemistry , medicine , alternative medicine , pathology

The title compound 1 is capable of undergoing intra‐ and intermolecular H 2 ‐elimination reactions as well as insertion into a Mn 2 (μ‐H) bridge. Its high reactivity is revealed in reactions with p‐MeC 6 H 4 SH, S 8 , tBuNC, MeCN and alkynes. The Mn‐Mn distance in 1 is 2.699(2) Å.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research