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Synthesis, Structure, and Reactivity of [Mn 2 (μ‐H) 2 (CO) 6 (μ‐Ph 2 PCH 2 PPh 2 )]
Author(s) -
Alonso Francisco J. García,
Sanz Manuel García,
Riera Victor,
Ruíz Miguel Angel,
Tiripicchio Antonio,
Camellini Marisa Tiripicchio
Publication year - 1988
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198811671
Subject(s) - reactivity (psychology) , intermolecular force , chemistry , manganese , crystallography , molecule , organic chemistry , medicine , alternative medicine , pathology
The title compound 1 is capable of undergoing intra‐ and intermolecular H 2 ‐elimination reactions as well as insertion into a Mn 2 (μ‐H) bridge. Its high reactivity is revealed in reactions with p‐MeC 6 H 4 SH, S 8 , tBuNC, MeCN and alkynes. The Mn‐Mn distance in 1 is 2.699(2) Å.