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Dications Based on a Hydrotris(phosphonio)borate Skeleton
Author(s) -
Schmidbaur Hubert,
Wimmer Thomas,
Reber Gabriele,
Müller Gerhard
Publication year - 1988
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198810711
Subject(s) - boron , phosphonium , chemistry , atom (system on chip) , hydrogen atom , crystallography , inorganic chemistry , polymer chemistry , organic chemistry , alkyl , computer science , embedded system
The first two dications having a [HBP 3 ] 2 ⊕ framework (1 and 2) —the boron atom is surrounded by three phosphonium centers and a hydrogen atom—were isolated as dibromides and characterized by X‐ray structure analysis. The stability of the two salts toward air and moisture is remarkable. The boron‐bonded H atom is exchanged for a D atom in alkaline D 2 O.