Dications Based on a Hydrotris(phosphonio)borate Skeleton | Zendy

Schmidbaur Hubert | Zendy; Wimmer Thomas | Zendy; Reber Gabriele | Zendy; Müller Gerhard | Zendy

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Dications Based on a Hydrotris(phosphonio)borate Skeleton

Author(s) -

Schmidbaur Hubert,

Wimmer Thomas,

Reber Gabriele,

Müller Gerhard

Publication year - 1988

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198810711

Subject(s) - boron , phosphonium , chemistry , atom (system on chip) , hydrogen atom , crystallography , inorganic chemistry , polymer chemistry , organic chemistry , alkyl , computer science , embedded system

The first two dications having a [HBP 3 ] 2 ⊕ framework (1 and 2) —the boron atom is surrounded by three phosphonium centers and a hydrogen atom—were isolated as dibromides and characterized by X‐ray structure analysis. The stability of the two salts toward air and moisture is remarkable. The boron‐bonded H atom is exchanged for a D atom in alkaline D 2 O.

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