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ENDOR Spectroscopy in Water: Reductions and Oxidations of Organic Compounds
Author(s) -
Bock Hans,
Hierholzer Bernhard
Publication year - 1988
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198810691
Subject(s) - chemistry , spectroscopy , redox , paramagnetism , scope (computer science) , characterization (materials science) , electron paramagnetic resonance spectroscopy , radical , nuclear magnetic resonance spectroscopy , inorganic chemistry , photochemistry , analytical chemistry (journal) , electron paramagnetic resonance , organic chemistry , materials science , nuclear magnetic resonance , nanotechnology , physics , quantum mechanics , computer science , programming language
The characterization of paramagnetic compounds in water by ENDOR spectroscopy was achieved by the use of special capillary tubes and optimal concentrations. This extension of the scope of application of this method is of great value for the study of biological redox reactions. The method was exemplified by determining the spectrum of the radical cation 2 , R = n ‐dodecyl. This compound was obtained by reduction of the viologen 1.