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Alkali‐Metal Hydrogen Tetraphosphides, M I HP 4 —the First Salts of Bicyclo[1.1.0]tetraphosphane
Author(s) -
Baudler Marianne,
Adamek Christoph,
Opiela Sylvia,
Budzikiewicz Herbert,
Ouzounis Dimitrios
Publication year - 1988
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198810591
Subject(s) - alkali metal , chemistry , intramolecular force , bicyclic molecule , hydrogen , medicinal chemistry , potassium , sodium , metal , white phosphorus , hydrogen atom , inorganic chemistry , stereochemistry , phosphorus , organic chemistry , alkyl
The first isolable reduction products of white phosphorus , the title compounds, are formed upon reaction of P 4 with naphthalenelithium or ‐sodium/potassium in protic solvents. They contain the HP 4 ⊖ion 1 , which, according to its NMR data, displays an unusual electronic structure. Intramolecular exchange of the endo hydrogen atom does not occur.