Triple Proton Abstraction from a 1‐Methylallyl Ligand on Thermolysis: Formation of a Hf 3 (C 4 H 4 ) Cluster | Zendy

Hessen Bart | Zendy; Spek Anthony L. | Zendy; Teuben Jan H. | Zendy

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Triple Proton Abstraction from a 1‐Methylallyl Ligand on Thermolysis: Formation of a Hf 3 (C 4 H 4 ) Cluster

Author(s) -

Hessen Bart,

Spek Anthony L.,

Teuben Jan H.

Publication year - 1988

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198810581

Subject(s) - ligand (biochemistry) , cluster (spacecraft) , chemistry , thermal decomposition , proton , stereochemistry , abstraction , crystallography , physics , computer science , organic chemistry , biochemistry , philosophy , quantum mechanics , receptor , epistemology , programming language

Complexes containing the unsubstituted 1,3‐butadiene‐1,4‐diyl ligand C 4 H 4 are very rare. Such a complex, 1 , has now been generated, surprisingly, by the unusual title reaction. In 1 , the C 4 H 4 ligand is linked unsymmetrically to three Cp * ClHf moieties; the two remaining Cl atoms each bridge two Hf centers (Cp * = η 5 ‐C 5 Me 5 ).

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