Alkyne Coordination to Organorhenium Oxides with Rhenium in High Oxidation States | Zendy

Felixberger Josef K. | Zendy; Kuchler Josef G. | Zendy; Herdtweck Eberhardt | Zendy; Paciello Rocco A. | Zendy; Herrmann Wolfgang A. | Zendy

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Alkyne Coordination to Organorhenium Oxides with Rhenium in High Oxidation States

Author(s) -

Felixberger Josef K.,

Kuchler Josef G.,

Herdtweck Eberhardt,

Paciello Rocco A.,

Herrmann Wolfgang A.

Publication year - 1988

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198809461

Subject(s) - alkyne , rhenium , oxide , chemistry , oxygen , catalysis , materials science , inorganic chemistry , organic chemistry

Methylrhenium( VII ) oxide 1 is an excellent starting substance for the synthesis of rhenium complexes with π‐alkyne ligands. As depicted below, the oxygen‐abstracting effect of polymer‐bound triphenylphosphane ℗ can be exploited for the production of the new complexes. 2. According to theoretical studies the existence of such Re V compounds was highly improbable. Reduction of 2 , R R′ Me, led to the first Re IV ‐alkyne complex 3.

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