Stabilization of 1,2,4,5‐Tetradehydrobenzene by Complexation at Two Nickel(0) Centers | Zendy

Bennett Martin A. | Zendy; Drage James S. | Zendy; Griffiths K. David | Zendy; Roherts Nicholas K. | Zendy; Robertson Glen B. | Zendy; Wickramainghe Wasantha A. | Zendy

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Stabilization of 1,2,4,5‐Tetradehydrobenzene by Complexation at Two Nickel(0) Centers

Author(s) -

Bennett Martin A.,

Drage James S.,

Griffiths K. David,

Roherts Nicholas K.,

Robertson Glen B.,

Wickramainghe Wasantha A.

Publication year - 1988

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198809411

Subject(s) - fluorobenzene , moiety , nickel , ring (chemistry) , chemistry , planar , stereochemistry , crystallography , organic chemistry , computer science , computer graphics (images) , benzene

The gold‐yellow Ni 2 0complex 1 of the unsubstituted 1,2,4,5‐tetradehydrobenzene C 6 H 2 is surprisingly easily accessible. 1 can be synthesized from [NiCl 2 (PPh 3 ) 2 ] and 1,2‐dichloro‐4‐fluorobenzene in only four steps. The C 6 H 2 Ni 2 moiety is planar, and the angles in the C 6 H 2 ring are partly deformed (Cy = cyclohexyl).

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