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Stepwise Synthesis and Crystal Structure of Tricarbonyl[pentakis(methylthio)cyclopentadienyl]‐manganese [{C 5 (SMe) 5 }Mn(CO) 3 ]
Author(s) -
Sünkel Karlheinz,
Motz Doris
Publication year - 1988
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198809391
Subject(s) - cyclopentadienyl complex , manganese , ligand (biochemistry) , crystal structure , chemistry , medicinal chemistry , crystallography , stereochemistry , organic chemistry , catalysis , receptor , biochemistry
Functionalized cyclopentadienyl ligands , with, e.g. one to five methylthio and four to zero chloro substituents are very promising species. Starting from [(C 5 Cl 4 Br)Mn(CO) 3 ] it has now been possible to synthesize all members of the series 1 which contain this ligand. The donor properties of the ligand increase with increasing number of MeS groups.