Conjugated and Nonconjugated Cyclopentenones by a Reaction Cascade from Methyl 6‐Oxo‐5‐phenyl‐1,3,4‐oxadiazine‐2‐carboxylate and 1,3‐Butadienes | Zendy

Hegmann Joachim | Zendy; Christl Manfred | Zendy; Peters Karl | Zendy; Peters EvaMaria | Zendy; von Schnering Hans Georg | Zendy

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Conjugated and Nonconjugated Cyclopentenones by a Reaction Cascade from Methyl 6‐Oxo‐5‐phenyl‐1,3,4‐oxadiazine‐2‐carboxylate and 1,3‐Butadienes

Author(s) -

Hegmann Joachim,

Christl Manfred,

Peters Karl,

Peters EvaMaria,

von Schnering Hans Georg

Publication year - 1988

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198809311

Subject(s) - cyclopentane , conjugated system , chemistry , derivative (finance) , cascade , carboxylate , stereochemistry , combinatorial chemistry , organic chemistry , chromatography , financial economics , economics , polymer

A novel, unusual route to cyclopentane derivative is opened up by the title reaction (one‐pot method) leading to 3 and/or 4. Five‐membered carbocycles occur in numerous natural products. Since no broadly applicable synthesis has been described so far, new methods are especially welcome.

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