A Topologically Chiral [2]Catenand | Zendy

Mitchell Dennis K. | Zendy; Sauvage JeanPierre | Zendy

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A Topologically Chiral [2]Catenand

Author(s) -

Mitchell Dennis K.,

Sauvage JeanPierre

Publication year - 1988

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198809301

Subject(s) - chirality (physics) , reagent , orientation (vector space) , stereochemistry , interlock , topology (electrical circuits) , crystallography , physics , combinatorial chemistry , mathematics , chemistry , chiral symmetry , combinatorics , geometry , quantum mechanics , organic chemistry , engineering , electrical engineering , nambu–jona lasinio model , quark

Two rings with preferred orientation as chain members which can interlock in two ways —that is the synthetic principle of topologically chiral [2]catenands 1. It has now been possible to prepare such a compound with 2 as the two individual rings by template synthesis via the copper( I ) complex. The chirality of the complex is confirmed by the 1 H‐NMR spectrum in the presence of Pirkles reagent.

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