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The First closo ‐Diphosphahexaborne, P 2 B 4 Cl 4
Author(s) -
Haubold Wolfgang,
Keller Willi,
Sawitzki Gisela
Publication year - 1988
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198809251
Subject(s) - heteroatom , boron , octahedron , crystallography , phosphorus , chemistry , crystal structure , organic chemistry , ring (chemistry)
Heteroatom‐boron clusters with phosphorus as heteroelement are formed in the copyrolysis of haloboranes and halophosphanes. Reaction of B 2 Cl 4 and PCl 3 furnishes mainly the diphosphahexaborane P 2 (BCl) 4 1 , which, in accord with the Wade rules, is a closo compound with an octahedral structure.