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Oxidative Coupling of Racemic and of Optically Active 3,6‐Di‐ tert ‐butylocta‐1,4,7‐triyne‐3,6‐diol
Author(s) -
Toda Fumio,
Okada Jyōji,
Mori Koji
Publication year - 1988
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198808591
Subject(s) - optically active , dimer , oxidative coupling of methane , diol , coupling (piping) , chemistry , polymer , stereochemistry , materials science , polymer chemistry , organic chemistry , methane , metallurgy
An optically inactive cyclic dimer 1 and an optically active polymer 2 are the products of the two title reactions. This dramatic difference in reactive behavior is of great importance with regard to the formation of natural, optically active polymers.