(Mesityl) 2 Ge(fluorenylidene)–Stabilization of a Ge–C Double Bond by Charge Transfer into an Aromatic System | Zendy

Lazraq Mohamed | Zendy; Escudié Jean | Zendy; Couret Claude | Zendy; Satgé Jacques | Zendy; Dräger Martin | Zendy; Dammel Ralph | Zendy

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(Mesityl) 2 Ge(fluorenylidene)–Stabilization of a Ge–C Double Bond by Charge Transfer into an Aromatic System

Author(s) -

Lazraq Mohamed,

Escudié Jean,

Couret Claude,

Satgé Jacques,

Dräger Martin,

Dammel Ralph

Publication year - 1988

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198808281

Subject(s) - delocalized electron , steric effects , mndo , electron delocalization , charge (physics) , atom (system on chip) , chemistry , double bond , resonance (particle physics) , electromagnetic shielding , photochemistry , computational chemistry , crystallography , atomic physics , materials science , stereochemistry , physics , molecule , organic chemistry , quantum mechanics , computer science , composite material , embedded system

Not only steric shielding but also resonance with a delocalized π‐electron system can help to stabilize nonclassical multiple bonds. Thus, despite high steric demands, 15 C atoms and the Ge atom of the title compound 1 lie nearly in the same plane. The experimental finding is in agreement with the result of a MNDO calculation.

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