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Alkyne(arene)cobalt, μ‐Alkynebis(arenecobalt), and μ‐Benzylidynetris(arenecobalt) from Arene/Cobalt Cocondensates
Author(s) -
Vasquez Luis,
Pritzkow Hans,
Zenneck Ulrich
Publication year - 1988
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198807061
Subject(s) - cobalt , toluene , benzene , alkyne , acetonitrile , chemistry , medicinal chemistry , polymer chemistry , organic chemistry , catalysis
The prototypic areneobalt complexes 1–3 are formed upon reaction of 2‐butyne (R′CH 3 ) with benzene (R H)/cobalt and toluene (R CH 3 )/cobalt cocondensates ( 1, 2 ) and from toluene/cobalt cocondensate in the presence of acetonitrile ( 3 ).