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Synthesis and Structure of (ET)[Ni{SC(CN)C(CN)S} 2 ], a Radical Cation Salt of Bis(ethylenedithio)tetrathiafulvalene
Author(s) -
Reith Walter,
Polborn Kurt,
Amberger Eberhard
Publication year - 1988
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198806991
Subject(s) - tetrathiafulvalene , chemistry , superconductivity , salt (chemistry) , radical ion , metal , crystallography , charge ordering , atmospheric temperature range , stereochemistry , charge (physics) , ion , condensed matter physics , molecule , physics , organic chemistry , meteorology , quantum mechanics
The compounds (ET) y (X) z are characterized by their broad range of structures and the realization of differing ET‐charge states. This makes them promising objects of study in an attempt to establish a correlation between structure and metallic or superconducting properties of organic compounds. The title compound 1 is an insulator at room temperature and exhibits no superconduction up to 1.7 K.