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[{Cp(CO) 2 Mn} 2 SPh] ⊕ , the First Sulfur Analogue of a Phosphanediyl (“Phosphinidene”) Complex
Author(s) -
Braunwarth Horst,
Huttner Gottfried,
Zsolnai Laszlo
Publication year - 1988
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198806981
Subject(s) - phosphinidene , sulfur , crystallography , atom (system on chip) , chemistry , manganese , trigonal crystal system , planar , materials science , inorganic chemistry , crystal structure , stereochemistry , organic chemistry , computer graphics (images) , computer science , embedded system
The sulfur atom in the title compound 1 is not pyramidally but trigonal‐planar coordinated . This compares with the known structure of phosphanediyl complexes and their homologues. But replacement of Ph by Et and of PF 6 ⊖by CIO 4 ⊖already leads to a complex with Mn‐‐Mn bonding and pyramidally coordinated sulfur atom.