[{Cp(CO) 2 Mn} 2 SPh] ⊕ , the First Sulfur Analogue of a Phosphanediyl (“Phosphinidene”) Complex | Zendy

Braunwarth Horst | Zendy; Huttner Gottfried | Zendy; Zsolnai Laszlo | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

[{Cp(CO) 2 Mn} 2 SPh] ⊕ , the First Sulfur Analogue of a Phosphanediyl (“Phosphinidene”) Complex

Author(s) -

Braunwarth Horst,

Huttner Gottfried,

Zsolnai Laszlo

Publication year - 1988

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198806981

Subject(s) - phosphinidene , sulfur , crystallography , atom (system on chip) , chemistry , manganese , trigonal crystal system , planar , materials science , inorganic chemistry , crystal structure , stereochemistry , organic chemistry , computer graphics (images) , computer science , embedded system

The sulfur atom in the title compound 1 is not pyramidally but trigonal‐planar coordinated . This compares with the known structure of phosphanediyl complexes and their homologues. But replacement of Ph by Et and of PF 6 ⊖by CIO 4 ⊖already leads to a complex with Mn‐‐Mn bonding and pyramidally coordinated sulfur atom.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research