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Cu II and Cu I Coordination Chemistry of a Novel O,O , Cl ‐Chelate Ligand. Formation of a Stable Carbonylcopper Complex
Author(s) -
Kläui Wolfgang,
Buchholz Elke
Publication year - 1988
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198805801
Subject(s) - comproportionation , copper , chemistry , ligand (biochemistry) , dissolution , chelation , methanol , crystallography , inorganic chemistry , nuclear chemistry , organic chemistry , receptor , biochemistry , electrode , electrochemistry
Dissolution of copper powder in methanol occurs in the presence of the bis(ligand)copper( II ) complex 1 when CO is admitted to the solution. The surprisingly stable Cu 1 complex 2 is formed in a comproportionation reaction. Complex 2 loses CO even upon drying under high vacuum.\documentclass{article}\usepackage{amssymb}\pagestyle{empty}\begin{document}$$[\{({\rm C}_6{\rm Me}_6){\rm RuCl}[{\rm P(O)(OMe)}_{2}]_{2}\}_{2}{\rm Cu}]\;{\bf 1}$$\end{document}