Coupling Metal Centers with Linearly Bridging, Delocalized, π‐Bonded Ligands:  p ‐Phenylenediimido Dimolybdenum Complexes | Zendy

Maatta Eric A. | Zendy; Devore David D. | Zendy

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Coupling Metal Centers with Linearly Bridging, Delocalized, π‐Bonded Ligands: p ‐Phenylenediimido Dimolybdenum Complexes

Author(s) -

Maatta Eric A.,

Devore David D.

Publication year - 1988

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198805691

Subject(s) - delocalized electron , bridging (networking) , metal , bridging ligand , crystallography , chemistry , ligand (biochemistry) , materials science , polymer chemistry , organic chemistry , computer science , computer network , biochemistry , receptor

Complex fragments having metal centers in high oxidation states can be coupled with the linearly bridging p ‐phenylenediimido ligand. This is demonstrated by the Mo 2 VIcomplex 1 , which could be prepared from [MoCl 4 (thf) 2 ] and p ‐phenylene diazide. Complex 1 can be reduced stepwise to isolable Mo 2 V , Mo 2 IV , and Mo 2 IIIcomplexes. Of special interest in connection with the synthesis of new conducting materials is a Mo 2 IIIcomplex.

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