Premium
C 5 O 2 (1,2,3,4‐Pentatetraene‐1,5‐dione), a New Oxide of Carbon
Author(s) -
Maier Günther,
Reisenauer Hans Peter,
Schäfer Ulrich,
Balli Heinz
Publication year - 1988
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198805661
Subject(s) - pyrolysis , oxide , photodissociation , carbon fibers , carbon oxide , chemistry , analytical chemistry (journal) , materials science , photochemistry , carbon monoxide , organic chemistry , composite number , composite material , catalysis
The carbon oxide 2, the longest so far, is stable in solution at room temperature. It is formed upon pyrolysis or photolysis of 1 . Its IR spectrum is in agreement with a linear or quasi‐linear structure. Compound 2 reacts, for example, with MeOH to give exclusively dimethyl allenedicarboxylate.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom