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A Pt 2 AgH 2 Complex
Author(s) -
Albinati Alberto,
Demartin Francesco,
Venanzi Luigi M.,
Wolfer Martin K.
Publication year - 1988
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198805631
Subject(s) - tetrahedron , crystallography , ether , chemistry , atom (system on chip) , core (optical fiber) , stereochemistry , physics , computer science , organic chemistry , optics , embedded system
An Ag(PtH) 2 spirocyclic structure is the core of complex 1 , which is formed upon addition of Ag[CF 3 SO 3 ] to two equivalents of trans ‐[PtH(C 6 Cl 5 )(PEt 3 ) 2 ] in ether. The PtAg distances and PtHAg angles are relatively small (2.791(1) Å and 107(2)°). The central Ag atom can be regarded as being coordinated in either a linear or a pseudo‐tetrahedral fashion.