[M(CO) 4 {CH 3 C(CH 2 PMe 2 ) 3 }], M  Ti, Zr, Hf, Complexes of Zerovalent Titanium, Zirconium, and Hafnium. First Structural Characterization of a Zr 0 ‐Carbonyl Complex | Zendy

Blackburn David W. | Zendy; Chi Kai Ming | Zendy; Frerichs Scott R. | Zendy; Tinkham Mary L. | Zendy; Ellis John E. | Zendy

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[M(CO) 4 {CH 3 C(CH 2 PMe 2 ) 3 }], M  Ti, Zr, Hf, Complexes of Zerovalent Titanium, Zirconium, and Hafnium. First Structural Characterization of a Zr 0 ‐Carbonyl Complex

Author(s) -

Blackburn David W.,

Chi Kai Ming,

Frerichs Scott R.,

Tinkham Mary L.,

Ellis John E.

Publication year - 1988

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198804371

Subject(s) - hafnium , zirconium , titanium , chemistry , inorganic chemistry , organic chemistry

The title compounds [M(CO) 4 (trmpe)], MTi, Zr, Hf, are orange‐red to deep violet. They can be prepared according to equation (a) in 20% (Hf‐complex) to 56% (Ti‐complex) yield. The Zr‐complex 1 has a 4 : 3 piano stool structure, with all bond lengths lying in the expected range (trmpe=CH 3 C(CH 2 PMe 2 ) 3 , DME=dimethoxyethane).

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