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2,4,6‐Ph 3 C 6 H 2 M (M Cu, Ag), Monomeric Cu 1 ‐ and Ag 1 ‐Complexes with Coordination Number 1
Author(s) -
Lingnau Regine,
Strähle Joachim
Publication year - 1988
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198804361
Subject(s) - steric effects , reactivity (psychology) , ligand (biochemistry) , crystallography , monomer , chemistry , molecule , metal , coordination number , coordination complex , stereochemistry , ion , polymer , organic chemistry , medicine , biochemistry , alternative medicine , receptor , pathology
The very unusual coordination number 1 of the metal , which results in a high reactivity toward small molecules like NO and CO, could be realized in the title compounds Ph 3 C 6 H 2 M (MCu: 1a ; MAg: 1b ) for the first time, thanks to the sterically very demanding aryl ligand “1,3,5‐triphenylphenyl”. The C1–metal distances are extremely short ( 1a : 1.890(6) Å; 1b : 1.902(3) Å).
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