Bis([1,2,5]thiadiazolo)[3,4‐ b ;3′,4′‐ e ]pyrazine, a Novel 14π‐Electron Heterocycle with High Electron Affinity | Zendy

Yamashita Yoshiro | Zendy; Saito Kenichi | Zendy; Suzuki Takanori | Zendy; Kabuto Chizuko | Zendy; Mukai Toshio | Zendy; Miyashi Tsutomu | Zendy

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Bis([1,2,5]thiadiazolo)[3,4‐ b ;3′,4′‐ e ]pyrazine, a Novel 14π‐Electron Heterocycle with High Electron Affinity

Author(s) -

Yamashita Yoshiro,

Saito Kenichi,

Suzuki Takanori,

Kabuto Chizuko,

Mukai Toshio,

Miyashi Tsutomu

Publication year - 1988

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198804341

Subject(s) - pyrazine , electron acceptor , electron , chemistry , electron affinity (data page) , crystallography , solid state , electron donor , electron transfer , acceptor , stereochemistry , materials science , photochemistry , organic chemistry , physics , molecule , condensed matter physics , catalysis , quantum mechanics

Although it contains no electron‐withrawing substituents and is not a 14π electron system, 1 can be reduced astonishingly easily. In the solid state, ribbons formed via SN contacts are present which are coupled by further SN interactions to give a three‐dimensional network. As an excellent electron acceptor, 1 could be suitable for the synthesis of novel organic conductors.

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