The Central Propellane Bond as Polymerizable CC Single Bond: Poly(tricyclo[4.2.0.0 2,7 ]octane‐1,7‐diyl)—a “Poly([1.1.1]propellane)” | Zendy

Schlüter ArnulfDieter | Zendy

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The Central Propellane Bond as Polymerizable CC Single Bond: Poly(tricyclo[4.2.0.0 2,7 ]octane‐1,7‐diyl)—a “Poly([1.1.1]propellane)”

Author(s) -

Schlüter ArnulfDieter

Publication year - 1988

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198802961

Subject(s) - propellane , octane , chemistry , polymerization , polymer chemistry , ring (chemistry) , single bond , polymer , crystallography , bicyclic molecule , stereochemistry , organic chemistry , group (periodic table)

The polymers 2 (R = t Bu, Ph; x > 18) have a rigid rodlike structure . These “poly[1.1.1]propellanes” are obtainable by anion‐initiated ( t BuLi, PhLi) ring‐opening polymerization, during which the central CC single bond in the corresponding [1.1.1]propellane 1 is broken. Of particular value in the structural proofs were the CP MAS 13 C‐NMR spectra.

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