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B 6 H 14 , a Dimeric B 3 H 7 ?
Author(s) -
Brellochs Bernd,
Binder Herbert
Publication year - 1988
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198802621
Subject(s) - valence (chemistry) , reactivity (psychology) , chemistry , crystallography , in situ , stereochemistry , organic chemistry , medicine , alternative medicine , pathology
“B 3 H 7 ” is formed in situ upon oxidation of B 3 H 8 ⊖and upon Cl ⊖ abstraction from B 3 H 7 Cl ⊖ . The NMR data indicate that the dimeric form B 6 H 14 is most likely present and has the probable valence structures AC , since the reactivity of B 6 H 14 suggests that the original B 3 H 7 units are intact.
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