[{(C 5 H 5 )Co} 3 (C 6 H 5 CHCHCH3)], an Organometallic Cluster with a Face‐Bridging Arene Ligand | Zendy

Wadepohl Hubert | Zendy; Büchner Klaus | Zendy; Pritzkow Hans | Zendy

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[{(C 5 H 5 )Co} 3 (C 6 H 5 CHCHCH3)], an Organometallic Cluster with a Face‐Bridging Arene Ligand

Author(s) -

Wadepohl Hubert,

Büchner Klaus,

Pritzkow Hans

Publication year - 1987

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198712591

Subject(s) - benzene , cluster (spacecraft) , chemistry , group 2 organometallic chemistry , bridging (networking) , ring (chemistry) , ligand (biochemistry) , metal , crystallography , stereochemistry , molecule , computer science , organic chemistry , computer network , biochemistry , receptor , programming language

In contrast to the two only known complexes with μ 3 ‐η 2 : η 2 : η 2 arene ligands and to benzene on densest packed metal surfaces the title complex 1 exhibits almost complete bond length equalization in the aromatic ring. 1 can be prepared in a one‐pot reaction from [CpCo(C 2 H 4 ) 2 ] and trans ‐β‐methylstyrene or allylbenzene.

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