High‐Pressure Synthesis and Crystal Structure of Neodymium( III ) Oxide Peroxide, Nd 2 O 2 (O 2 ) | Zendy

Range KlausJürgen | Zendy; Stadler Maximilian | Zendy; Rau Franz | Zendy; Klement Ulrich | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

High‐Pressure Synthesis and Crystal Structure of Neodymium( III ) Oxide Peroxide, Nd 2 O 2 (O 2 )

Author(s) -

Range KlausJürgen,

Stadler Maximilian,

Rau Franz,

Klement Ulrich

Publication year - 1987

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198711741

Subject(s) - neodymium , peroxide , oxygen , chemistry , crystal structure , oxide , oxygen pressure , inorganic chemistry , crystallography , laser , organic chemistry , optics , physics

The most oxygen‐rich compound so far reported for the system neodymiumoxygen was obtained by high‐pressure synthesis from Nd 2 O 3 /KO 2 mixtures. Respite the composition NDO 2 , the X‐ray crystal structure analysis revealed at a neodymium( III ) oxide peroxide and not a neodymium(iv) dioxide was present. Nd 2 O 2 (O 2 ) is remarkably stable at normal pressure and only undergoes transformation to Nd 2 O 3 at 420°C with loss of oxygen.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research